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Fluids

Liquid to gas at constant pressure



When we keep the pressure constant and heat up a quantity of liquid substance (e.g. water) then its temperature rises. In the figure below we start at the phase indicate by 1. The process of rising temperature is indicated by the horizontal line. At a certain point we arrive at the line which separates the liquid phase of the substance from its gaseous phase. At that point, the boiling point of the substance, the temperature stops rising although we continue to supply heat to the quantity of liquid substance. This heat is used for evaporating the liquid into gas. Only after all substance is evaporated the temperature starts rising again and we do reach the temperature indicated by 2 in the figure below.

Liquid to gas at constant pressure


The opposite proces, from 2 to 1, happens when we cool a gas under constant pressure. At the boiling point further cooling does not lower the temperature until all gas is condensated. Only after full condensation the temperature starts lowering again and we do reach the temperature indicated by 1 in the figure above.


phase transitions